Robust dye-sensitized overall water splitting system with two-step photoexcitation of coumarin dyes and metal oxide semiconductors.

Visible light water splitting using dye-sensitized oxide semiconductors.

Researchers are intensively investigating photochemical water splitting as a means of converting solar to chemical energy in the form of fuels. Hydrogen is a key solar fuel because it can be used directly in combustion engines or fuel cells, or combined catalytically with CO(2) to make carbon containing fuels. Different approaches to solar water splitting include semiconductor particles as phot...

Improving the efficiency of water splitting in dye-sensitized solar cells by using a biomimetic electron transfer mediator.

Photoelectrochemical water splitting directly converts solar energy to chemical energy stored in hydrogen, a high energy density fuel. Although water splitting using semiconductor photoelectrodes has been studied for more than 40 years, it has only recently been demonstrated using dye-sensitized electrodes. The quantum yield for water splitting in these dye-based systems has, so far, been very ...

Ultrafast Electron Injection Dynamics of Photoanodes for Water- Splitting Dye-Sensitized Photoelectrochemical Cells

Efficient conversion of solar energy into useful chemical fuels is a major scientific challenge. Water-splitting dyesensitized photoelectrochemical cells (WS-DSPECs) utilize mesoporous oxide supports sensitized with molecular dyes and catalysts to drive the water-splitting reaction. Despite a growing body of work, the overall efficiencies of WS-DSPECs remain low, in large part because of poor e...

Artificial evolution of metal-free coumarin dyes for dye sensitized solar cells

Investigation of Indigo/thioindigo Tandem Dye-Sensitized Solar Cells

In this paper we used two free-metal organic dyes (dye 1 and dye 2) based on indigo and thioindigo with cyanoacrylic acid as the electron acceptor group. The proposed dyes were sensitized from naphalene as the starting material by standard reactions and characterized by different analytical techniques and UV-Visible spectroscopy after purification. Spectrophotometric measurements of the organic...